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But don't fall for schemes that claim they won't still be introducing CO2 into the atmosphere. The energy comes from the formation of CO2 and it takes more energy than it produces to split them up again. It can't physically work or we would have perpetual energy by making CO2, turning it back into carbon and burning it again.
The system already captures the CO2. Capturing it is the hard part of sequestration. Once captured, it can be pumped deep into the earth where it remains a liquid, and stays put.