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Please go read up some on the quantum energy states of CO2.Big deal. Absorption of surface infrared does not warm the Earth. Remember, the surface is cooled by emitting the infrared.
Big deal. Air can be warmed by contact with the surface as well.
Nothing more than another for the surface to warm the air above it. That does not warm the Earth.
WRONG. You are creating energy out of nothing. If the CO2 does emit the same energy, then NONE of that energy went into surrounding molecules before energy was emitted.
CO2 is the same material. It always has the same properties.
What warming? No gas or vapor can warm the Earth using infrared light emitted from the Earth's surface.
CO2 even if it absorbs a 15 um photon, will likely never emit a photon, because it will come into contact with millions of other atoms and
molecules, long before the 10 to 50 milliseconds elapse for spontaneous decay.
Weather you like it or not, the 667 cm-1 energy level caused from the 15 um photon, does represent a minor amount of energy.
and the first law of thermodynamics states that that energy must be accounted for.