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If you think atmospheric absorption in the infrared has been tested and the results of those test publishedAre you now actually admitting you just have an opinion based on an irrelevant piece of research done some 60 years ago on a subject that has now been thoroughly studied and shows that this idea of CO₂ being a brake on warming is total BS?
then cite those papers? Until you can cite them, the empirical data from the 50's and 60's stands.
Also the first law of thermodynamics is a bit of a hurdle to overcome, "energy cannot be created or destroyed!"
if all the energy is already in the band is already absorbed, there is simply no additional energy to absorb.
The best added CO2 could do would be to pick up some minor bands on the edges, but that would start to run into
where H2O absorbs.