At some level, yes! Physics and quantum energy states. It was one of the reasons I was originally skeptical of AGW.
CO2 is quite picky about what optical wavelengths it absorbs, to excite CO2, usually requires a two step process with nitrogen.
To keep the CO2 from hitting a population inversion at 667 cm-1, usually requires the addition of helium.
Since there is little atmospheric helium, the CO2 would quickly saturate.
Yes there would be some pressure broadening, but the energy passed would be greatly reduced.
Research methods are about taking steps to not fool yourself, it is very easy to see something you want to see, or expect to see.
At a chemical level, the brain likes to find order, even where none appears to exists.
In many people the serotonin levels increase when looking at abstract art, because the brain finds order in the abstract.
These concepts of how to research a topic without bias, extend to all the sciences, it is the core of the scientific method!