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Satellites measures the surface. In case it isn't obvious, it's not like all of the CO2 stays in the top 10cm of the ocean. The surface measurements indicate what's happening in the top layers of the ocean.
Direct measurements are taken at a variety of depths. E.g. the ESTOC site near the Canary Islands has its pH and CO2 sensors close to the surface (1.5m); E2-M3A is also very close (10m depth). Station M has multiple instruments in a column, and collects pH and pCO2 data up to 2000m below the surface.
Anyway... There are lots of organisms in the surface layers of the ocean. They form shells out of CaCO3 which settles on the ocean floor. As the oceans become more acidic, the CaCO3 produced by those near-surface organisms is increasingly dissolved rather than forming sediment, and this changes the mineral composition of the ocean floor. Thus, even if we are only talking about what's happening on the upper layers of the oceans, it's a change whose full impacts we really ought to try and understand.
By the way, ocean waters do this crazy thing called "circulate." It does take time, and some of the CO2 goes back into the atmosphere before those waters circulates into deeper ocean waters. Eventually the increases in CO2 and changes in pH in the ocean already propagate to lower layers, and this spreads out the impact. The more CO2 we emit, the larger the impact over time. See how that works?
Well, I guess you'd better grab a new napkin. You're simultaneously saying "it's only the surface!" but your math assumes that the CO2 is evenly spread through the entire ocean. Which is it? (And, of course, it didn't occur to you to calculate how much we will add by 2050, 2100, 2200...)
Anyway. The empirical evidence is clear that it is not irrelevant. The added CO2 is increasing pH levels in a layer of the ocean which is responsible for perhaps 25% of the ocean floor sediment. Trace amounts still matter, most notably when dealing with organisms that may not have time to adapt.
The point is either;
1, It is in the surface only and thus having a slight but detectable effect.
or
2, It is all the way down and thus so tiny as to be utterly inconsequential if detecable at all.