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Chemical weapons have been in use since ww1, by major countries banned or not. However they stopped being effective post ww1 as the major losses from mustard gas due to numerous soldiers being crammed in a trench led countries to re organize their tactics, which killed effectiveness of chemical attacks.
They kill less than plain bombs or missiles, they are for the shock effect to de moralize an opposing army more than to kill them, unless they returned to ww1 style trench warfare.
Gonna hafta disagree with you there. They are weapons of mass destruction. Chemical and biological weapons have the potential to kill MASSIVE numbers of people in absolutely horrific ways.